Charles Schwab & Co. is making a charge at the overseas market, and Robert Duste is helping lead it.

The senior vice president has been with the company since 1984. Having played a key role in the discount brokerage leader's push to the forefront of the U.S. on-line investment market, Mr. Duste is looking to recreate some of that success as head of technology for what Schwab calls its international enterprise.

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