First Union Corp., in the midst of a top-level reorganization, has settled on a lineup for its operations and technology divisions, and Bank One Corp. has reaped some of the spoils.

P. Sue Perrotty, a First Union insider who most recently led the general banking group's Pennsylvania/Delaware region, will take over operations for the Charlotte, N.C., company, reporting to chief executive officer G. Kennedy Thompson, and will be part of the executive management team, the company said Wednesday.

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