First Union Corp. gave president John R. Georgius the additional title of chief operating officer on Tuesday and named two other executives vice chairmen of the $235 billion-asset company. Mr. Georgius, 54, takes on a position which was previously unfilled.

In addition, First Union elevated G. Kennedy Thompson, 47, and Charles L. Coltman 3d, 55, from executive vice president to vice chairmen.

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